Facilities
Large-scale facilities

SPRINT

General informations

Location
FERMI Experimental Hall, Trieste, Italy
Main techniques and methods
Photoemission Spectroscopy (PES,ARPES, tr-ARPES), Spin polarimetry, Time resolved optical spectroscopy
Key instumentation
- Femtosecond laser (1030 nm, 1 MHz)
- Optical Parametric Amplifier (630 –16000nm)
- High Harmonics Generation beamline (16-70 eV)
- Emispherical Analyzer,
- Vectorial Mott Detector(s)
- In-situ sample preparation UHV chamber
- UHV transfer of samples from PLD and MBE of APE-NFFA beamlines

SPRINT is an High Harmonics Generation laboratory for spin and time resolved photoemission spectroscopy

The SPRINT lab is based on a double-branch high harmonic generation (HHG) beamline producing 150 fs pulsed in the range 16 –70 eV with up to 400 khz repetition rate, 1012photons/sec and energy resolution down to 20 meV.

Technical description

The SPRINT lab is based on a double-branch high harmonic generation (HHG) beamline producing 150 fs pulsed in the range 16 – 70 eV with up to 400 kHz repetition rate, with 1012photons/sec and energy resolution down to 20 meV. The HHG generation is obtained by means of a Yb:KGW laser source (PHAROS), able to produce pulses at 1030 nm, with time duration of 300 fs, variable repetition rate from 50 kHz up to 1 MHz, pulse energy of 400 μJ and average power up to 20 Watts.  The laser can seed two optical parametric amplifiers (OPAs), configured for operation with 40 μJ/pulse or 360 μJ/pulse. They allow for a tunable output in the range 630-2600 nm (ORPHEUS HP) and in the range 1350-4500 nm (ORPHEUS ONE HP), which is also equipped with a DFG crystal to extend the output to 16 mm, with a conversion efficiency around 10-20 %, depending on wavelength. The production of harmonics (up to the fifth) is also possible, producing 515 nm (2nd), 343 nm (3rd), 257 nm (4th) and 206 nm (5th).

The end station is equipped with standard surface preparation tools and with a Scienta SES-2002 electron spectrometer for ARPES experiments. A vectorial Mott detector(s) setup (total yield mode) is able to measure the spin polarization of the secondary electrons. Cryogenic temperature control and extremely low stray magnetic field sample environment are implemented. The samples are prepared in the annex sample preparation module that will also receive samples grown and characterized at NFFA-Trieste APE stations via a UHV shuttle.

Development of new methods, instrumentation, software

Instrumentation: The high harmonic generation system was designed and realized in collaboration with Sincrotrone Trieste and with IFN-­CNR (Padova, L. Poletto); a new method to increase gas pressure for generation in vacuum, and the monochromator concept contribute to reach optimal energy resolution at high repetition rate. The optical system and the delay line for laser pulses were implemented in the acquisition system for pump/probe spectroscopy. A vacuum suitcase has been developed and realized, allowing the transportation in ultra-high vacuum (10‐11 mbar, 20 hours) to and from growth and spectroscopy facilities. The Mott detector has been equipped with a new home-­made acquisition and control system, specifically designed (collaboration with Sincrotrone Trieste) for twin operation (static and pump-­probe). The whole measurement apparatus “Ultraspin” has been designed, developed in house, and commissioned also with contribution of a Marie Curie fellowship.

Software: The acquisition program for remote control and motorization of the HHG beamline has been developed in house. A specific software for Mott detector has been developed for high repetition measurements, and also an implementation of Scienta software for time resolved experiment has been provided (both in collaboration with Sincrotrone Trieste).

Research Activity

The research activity of the group is focused on electronic and magnetic properties of less than 3D systems (surfaces and interfaces), quantum materials and highly correlated systems. The strategic role of SPRINT is to enable the photoemission spectroscopy community to exploit ultrashort pulses in the linear response regime, and explore the non-­linear regime by integrating photon-­in photon-­out methods, favoring advanced use of FEL sources. Building up on a solid knowledge of electron spectroscopies developed at APE beamline and at synchrotron sources (see projects and funding), the design, construction and operation of the NFFA-­SPRINT facility represent a development of the NFFA project (WWW.Trieste.NFFA.eu) performed in collaboration with T-­Rex (Elettra-­ST). NFFA aims at continuously developing and operating an integrated users access infrastructure to nano-­‐foundry services (growth, characterization, theory, fine analysis, FAIR data management) along with APE­‐LE, APE‐HE and with partial involvement of other IOM activities (EM, MBE­‐nanowires), using dedicated resources from national and European grants, under the responsibility and coordination of Giorgio Rossi (Dip. di Fisica UNIMI and IOM). Commissioning of the SPRINT‐lab (2017‐2018) achieved performances well above specifications, with first user experiment in 2019. Future experiments will address the spin dynamics in semiconductors and the hidden metallic phase in manganites, following results obtained on half metallic LSMO.

Projects

MIUR-FOE, NFFA -Trieste, 2016-2020

Horizon2020, NFFA Europe Pilot (NEP), 2021-2025

Horizon 2020 FET Open, SINFONIA, 2021-2024

Main collaborations

  • Elettra-Sincrotrone, Trieste, Italy
  • Università di Milano, Italy
  • SPIN-CNR, Genova, Italy
  • IFN-CNR, Milano, Italy
  • Università di Roma La Sapienza, Italy
  • École Polytechnique-Palaiseau, Paris, France
  • TUM, Munich, Germany
  • Chemistry Department, Univ. of Princeton, USA
  • Diamond Light Source, Didcot, UK
  • Imperial College London, UK

Key publications

Chemical Reviews, 121-5:2816-2856, 2021 doi:10.1021/acs.chemrev.0c00616

Angle Spin and Depth Resolved Photoelectron Spectroscopy on Quantum Materials

King P.D.C., Picozzi S., Egdell R.G., Panaccione G.
Structural Dynamics, 7-1, 2020 doi:10.1063/1.5131216

Coherent narrowband light source for ultrafast photoelectron spectroscopy in the 17-31 eV photon energy range

Cucini R., Pincelli T., Panaccione G., Kopic D., Frassetto F., Miotti P., Pierantozzi G.M., Peli S., Fondacaro A., De Luisa A., De Vita A., Carrara P., Krizmancic D., Payne D.T., Salvador F., Sterzi A., Poletto L., Parmigiani F., Rossi G., Cilento F.
Science Advances, 5-7, 2019 doi:10.1126/sciadv.aaw5805

Nanoscale transient gratings excited and probed by extreme ultraviolet femtosecond pulses

Bencivenga F., Mincigrucci R., Capotondi F., Foglia L., Naumenko D., Maznev A.A., Pedersoli E., Simoncig A., Caporaletti F., Chiloyan V., Cucini R., Dallari F., Duncan R.A., Frazer T.D., Gaio G., Gessini A., Giannessi L., Huberman S., Kapteyn H., Knobloch J., Kurdi G., Mahne N., Manfredda M., Martinelli A., Murnane M., Principi E., Raimondi L., Spampinati S., Spezzani C., Trovò M., Zangrando M., Chen G., Monaco G., Nelson K.A., Masciovecchio C.
Physical Review B, 100-4, 2019 doi:10.1103/PhysRevB.100.045118

Transient quantum isolation and critical behavior in the magnetization dynamics of half-metallic manganites

Pincelli T., Cucini R., Verna A., Borgatti F., Oura M., Tamasaku K., Osawa H., Lee T.-L., Schlueter C., Günther S., Back C.H., Dell'Angela M., Ciprian R., Orgiani P., Petrov A., Sirotti F., Dediu V.A., Bergenti I., Graziosi P., Miletto Granozio F., Tanaka Y., Taguchi M., Daimon H., Fujii J., Rossi G., Panaccione G.
Physical Review B, 99-16, 2019 doi:10.1103/PhysRevB.99.165101

Valence band hard x-ray photoelectron spectroscopy on 3d transition-metal oxides containing rare-earth elements

Takegami D., Nicolaï L., Koethe T.C., Kasinathan D., Kuo C.Y., Liao Y.F., Tsuei K.D., Panaccione G., Offi F., Monaco G., Brookes N.B., Minár J., Tjeng L.H.
Faraday Discussions, 213:215-230, 2019 doi:10.1039/c8fd00108a

Spectroscopic elucidation of ionic motion processes in tunnel oxide-based memristive devices

Baeumer C., Heisig T., Arndt B., Skaja K., Borgatti F., Offi F., Motti F., Panaccione G., Waser R., Menzel S., Dittmann R.
Part F85-EUVXRAY 2018 (2018) doi:10.1364/EUVXRAY.2018.EW2B.5

A novel high order harmonic source for time- and angle- resolved photoemission experiments

Miotti P., Cilento F., Cucini R., De Luisa A., Fondacaro A., Frassetto F., Kopic´ D., Payne D., Sterzi A., Pincelli T., Panaccione G., Parmigiani F., Rossi G., Poletto L.
Physical Review B, 97-15, 2018 doi:10.1103/PhysRevB.97.155102

Revisiting the origin of satellites in core-level photoemission of transparent conducting oxides: The case of n -doped SnO2

Borgatti F., Berger J.A., Céolin D., Zhou J.S., Kas J.J., Guzzo M., McConville C.F., Offi F., Panaccione G., Regoutz A., Payne D.J., Rueff J.-P., Bierwagen O., White M.E., Speck J.S., Gatti M., Egdell R.G.
Nature Communications, 8, 2017 doi:10.1038/ncomms16051

Quantifying the critical thickness of electron hybridization in spintronics materials

Pincelli T., Lollobrigida V., Borgatti F., Regoutz A., Gobaut B., Schlueter C., Lee T.-L., Payne D.J., Oura M., Tamasaku K., Petrov A.Y., Graziosi P., Miletto Granozio F., Cavallini M., Vinai G., Ciprian R., Backl C.H., Rossi G., Taguchi M., Daimon H., Van Der Laan G., Panaccione G.
Review of Scientific Instruments, 87-3, 2016 doi:10.1063/1.4943255

Design and optimization of a modular setup for measurements of three-dimensional spin polarization with ultrafast pulsed sources

Pincelli T., Petrov V.N., Brajnik G., Ciprian R., Lollobrigida V., Torelli P., Krizmancic D., Salvador F., De Luisa A., Sergo R., Gubertini A., Cautero G., Carrato S., Rossi G., Panaccione G.